The influence of learning emotions on learning behaviors in college physical education is directly reflected in learning efficiency. Based on this research background, the paper applies a mathematical, statistical model to structural equation modeling of the emotional situation of students in a school's physical education curriculum. The study results found that college students have lower positive emotional attitudes towards college physical education courses. Thus, students’ mood is affected by the. For this reason, we should eliminate students’ resistance and fear of college physical education courses and promptly correct students’ unhealthy learning emotions about college physical education courses. In this way, it helps students correct their negative feelings about college physical education courses.