In order to develop students’ concentration in the classroom, this paper proposes to analyze students’ learning concentration from three dimensions, where the superiority of the random forest classification algorithm is found in the dimension of head posture estimation so that students’ attention ranges can be analyzed. For data acquisition, the OpenPose platform is used for real-time detection of body, foot, hand, and face key points. A comprehensive evaluation study of students’ concentration levels in the classroom was achieved through an effective algorithm. Finally, the multimodal information fusion algorithm was investigated, and it was concluded that the weights could be calculated by hierarchical analysis to achieve a comprehensive evaluation of students’ learning concentration. By analyzing the course data of 12 students, the distribution of SFR values, Yaw angle and Pitch angle distribution, PERCLOS value distribution, and correct/error rate distribution of answers were counted, and the final scores of respective learning engagement were obtained as 0.91, 0.62, 0.80, 0.36, 0.82, 0.73, 0.81, 0.63, 0.81, 0.81 The model scores were compared with the expert scores, and the accuracy rate reached 98.6%, which proved that the model proposed in this paper is effective and can correctly reflect the real state of students’ learning in the classroom.