Under the guidance of the new vocational education method of artificial intelligence, this paper divides the skill-based society into skill-based organizations, and constructs a knowledge dynamic equilibrium model based on superimposed knowledge fields. The knowledge-explicit module of skill-based talent flow and the external dynamic equilibrium module are integrated to achieve the evolutionary modeling of knowledge resources in skill-based organizations. Based on the discussion of the new vocational education law, the characteristic models of intellectual resource development, knowledge dynamic growth, group evolution and talent motivation in skill-based organizations are proposed respectively. The simulation analysis of the knowledge dynamic equilibrium network is combined with the analysis of influencing factors to inspire the education of higher vocational colleges and universities under the new vocational education method. As measured by the data, the average path length mean values of the intra-organizational knowledge network when N=160, 260, 330 are 2.2761, 2.4437 and 2.5394, respectively, which indicates that skilled talents have a strong willingness to interact with each other and share knowledge. The construction of skill-based organizations should fully create a strong environment for talent exchange and focus on cultivating students’ willingness and ability to communicate in vocational education.