This paper puts forward the support technology of fast charging supply and demand matching in charging stations and analyzes the common large-capacity electrochemical energy storage technical parameters in charging stations. For the safety of electric vehicle charging, the thermal reaction and thermal runaway processes of power batteries are introduced. Design the electric vehicle charging state monitoring and safety warning methods, and select the multi-timescale ARIMA algorithm to build the electric vehicle charging safety warning model. The sliding window method is used to process the residual mean and residual standard deviation of electric vehicle charging data to improve prediction data and decrease the chance of misjudging pre- and alarms. Combined with the evaluation standard of the safety early warning model, set reasonable pre- and alarm thresholds using the residual analysis method. The safety warning model designed in this paper is verified by different charging fault warnings. Different charging fault warning examples show that the ARIMA-based charging safety early warning model proposed in this paper can be good for the charging facility’s output voltage, output current, and charging module temperature faults for early warning to ensure that the warning is carried out before the alarm of the actual fault information, to protect the charging safety of electric vehicles.