With the development of China’s economy, the application of industrial radiation flaw detection technology is becoming more and more widespread, and the radiation monitoring and protection of flaw detection work has become an important topic in the field of radiation safety and protection. This paper uses pyroelectric technology to track X-ray radiation levels in the environment. It also chooses the scale curve method for calibrating the pyroelectric dosimeter and figures out the scale factor at the same time. The neutron and photon dimensions are used to evaluate the personal dose equivalent. The applicable range of pyroelectric dosimeters is calculated and the method is applied for radiation dose monitoring in industrial X-ray flaw detection rooms. Concrete wall shielding is used to determine the design parameters of the flaw detection room and the location of the distribution points to improve the shielding capacity of the flaw detection room and control the radiation intensity. The monitoring value of the operation position of the flaw detection room of Leshan Leboiler Enterprises in 2018 was 258.2, which was 73 higher than that of 2019. The results of the on-site monitoring of the absorbed dose rate of the ambient air in the flaw detection room showed that the average absorbed rate ranged from 0.015 to 0.546 μSv/h, which was lower than the standard of 2.5 μSv/h, and the shielding capacity of the flaw detection room was better, and the intensity of the radiation could be effectively controlled.