China’s library and intelligence organizations have a long history, rich resources and excellent talents and have played an important role in various consulting services. They are currently facing fierce market competition, making it challenging to meet users’ needs. This paper first establishes the principles of digital information resource services, based on the principles, reference to the ACSI model and considers a number of indicators to establish a scientific user satisfaction measurement model of digital resources in line with the actual development of library intelligence. The relationship between intelligent library intelligence and user satisfaction is investigated by combining a measurement model and structural model. Relevant hypotheses are proposed, research variables are identified, and empirical analysis is utilized to evaluate the model’s practicability. The results of the empirical research show that the hypotheses that library intelligence services can improve user satisfaction are verified through the path significance test, and after analysis, we know that the standardized path coefficients of paths 1, 3-7 are 0.526, 0.395, 0.426, 0.536, 0.163, and 0.168, respectively, which are greater than 0 and the P-value is less than 0.05 so that the hypotheses 1, 3-7 are valid. Intelligent library intelligence-related variables have a positive effect on user satisfaction improvement.